We present the mass-metallicity relation (MZR) for a parent sample of 604 galaxies at $z=5.34-6.94$ with [Oiii] doublets detected, using the deep JWST/NIRCam wide field slitless spectroscopic (WFSS) observations in 26 quasar fields. The sample incorporates the full observations of 25 quasar fields from JWST Cycle 1 GO program ASPIRE and the quasar SDSS J0100+2802 from JWST EIGER program. We identify 204 galaxies residing in overdense structures using the friends-of-friends (FoF) algorithm. We estimate the electron temperature of $2.0^{+0.3}_{-0.4}\times10^4$ K from the H$\gamma$ and [$O$iii]$_{\lambda4363}$ lines in the stacked spectrum, indicating a metal-poor sample with median gas phase metallicity 12+$\log(\mathrm{O/H})=7.65^{+0.26}_{-0.15}$. With the most up-to-date strong line calibration based on NIRSpec observations, we find that the MZR shows a metal enhancement of $\sim0.2$ dex at the high mass end in overdense environments. However, compared to the local Fundamental Metallicity Relation (FMR), our galaxy sample at $z>5$ shows a metal deficiency of $\sim0.2$ dex relative to FMR predictions. We explain the observed trend of FMR with a simple analytical model, and we favor dilution from intense gas accretion over outflow to explain the metallicity properties at $z>5$. Those high-redshift galaxies are likely in a rapid gas accretion phase when their metal and gas contents are in a non-equilibrium state. According to model predictions, the protocluster members are closer to the gas equilibrium state than field galaxies and thus have higher metallicity and are closer to the local FMR. Our results suggest that the accelerated star formation during protocluster assembly likely plays a key role in shaping the observed MZR and FMR, indicating a potentially earlier onset of metal enrichment in overdense environments at $z\approx5-7$.